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STUDY ON THE MECHANISM OF GRAPHITIZATION IN MOLTEN CAST IRON PROMOTED BY ELECTROPULSE DISCHARGE

G.W.Chang

金属学报(英文版)

From the points of both molten cast iron structure and the appearing ratio of electrons in outer-layer of different atoms, analysis on enhancement mechanism of graphitization ability after processing of the iron by pulse electric discharge has been made, and the theory has been proofed by corresponding experiments. The results show that when the molten cast iron is being processed by pulse electric discharge, both the size of crystal embryos that composed by Fe and C atoms as well as the number of clusters can be reduced, even be separated by such discharging; consequently results in the segregation of C atoms in the molten cast iron near the cathode of discharging. The nucleation of graphite in these areas of the iron has been promoted at the discharging temperature; even though such degree has not been reached, the mast favorablenucleation conditions of graphite can be at least created. Under the preconditions of not breaking up the graphite crystal embryos, with proper adjustment of discharging frequency, the stronger of the electric field and the longer of the pulsation treatment time are, the more graphitization ability of the molten cast iron is. The theoretical analysis on the above rules consists well with experimental results.

关键词: pulsed electric field , null , null

高压脉冲电场对餐厨垃圾发酵产气特性的影响

张立东 , 米天朋 , 李尧松 , 王旭明 , 刘晓婷 , 张兰河

硅酸盐通报

为了实现餐厨垃圾的减量化,采用高压脉冲电场(pulsed electric field,PEF)对餐厨垃圾预处理后接种厌氧污泥进行厌氧发酵,考察pH、挥发性有机酸(VFA)与日产气量的关系,分析PEF对餐厨垃圾厌氧发酵的影响.结果表明:在温度50℃条件下,日产气量与pH成正比例变化趋势,与VFA呈反比例关系.经PEF(电场强度为9.0 kV·cm-1)预处理后,接种20%厌氧污泥,餐厨垃圾干物质产气量(285.1 mL·(g·TS)-1)与TS去除率(28.5%)均达到最高,高于无PEF预处理餐厨垃圾的干物质产气量(267.3 mL·(g· TS)-1)和TS去除率(26.8%).PEF能够杀死餐厨垃圾样品中的微生物,改善接种后微生物的生存环境,减少微生物发生种间竞争的概率,利于提高产气量.

关键词: 餐厨垃圾 , 厌氧发酵 , 高压脉冲电场 , 挥发性脂肪酸

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